Liverpool has already secured its place in the last 16 of the Champions League with those teams in the playoffs now discovering their opponents.
The Reds cruised to top spot in the group stage despite losing to PSV with a much changed line up and will not have to navigate a two-legged playoff next month.
Arne Slot was able to rest his star players in Eindhoven with one eye on this weekend's Premier League encounter with Bournemouth. His side is joined by the likes of Arsenal and Aston Villa in the last 16 but Manchester City still has plenty of work to do and now faces Real Madrid.
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Pep Guardiola's men needed a win on the final round of group stage matches against Club Brugge to avoid a shock elimination and fell behind in the first half at the Etihad. But City fought back in the second half to secure its place in the play off round.
Arsenal ended its group stage campaign with victory over Girona while Villa's thrilling victory over Celtic was enough to secure eighth spot in the table.
An all-French tie between PSG and Brest will take place in the playoffs, while Benfica will face Monaco as each team looks to set up a last 16 tie with either Liverpool or Barcelona. The official draw for the Last 16 will take place next month.
Teams guaranteed place in last 16 - Liverpool, Barcelona, Arsenal, Inter Milan, Atletico Madrid, Bayer Leverkusen, Lille, Aston Villa.
Champions League play-off round draw
Brest vs Paris Saint-Germain
Monaco vs Benfica
Juventus vs PSV
Feyenoord vs AC Milan
Manchester City vs Real Madrid
Celtic vs Bayern Munich
Club Brugge vs Atalanta
Sporting vs Borussia Dortmund
